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A solvent-free post-treatment process known as vapor phase infiltration (VPI) is used to engineer the organic solvent reverse osmosis (OSRO) performance of polymer of intrinsic microporosity 1 (PIM-1) membranes via infiltration of trimethylaluminum (TMA) metal-organic vapor. The infiltration of inorganic aluminum constituents hybridizes the pure polymer PIM-1 into an organic-inorganic material (AlOxHy/PIM-1) with enhanced chemical stability. A homogenous distribution of inorganic loading in PIM-1 is achieved due to the reaction-limited infiltration mechanism, and the OSRO performance is enhanced as a result. OSRO separations of ethanol/isooctane mixtures using these membranes are shown to be capable of breaking the azeotropic composition with a separation factor for ethanol over isooctane greater than 5 and an ethanol permeance of 0.1 Lm–2h–1bar–1. Thus, these organic-inorganic hybrid membranes created via VPI show promise as an alternative method for separating azeotropic liquid mixtures.more » « less
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Kim, Dae Seok; Lee, Young-Joo; Wang, Yuchen; Park, Jinseok; Winey, Karen I.; Yang, Shu (, ACS Applied Materials & Interfaces)
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Chen, Wei-Hsi; Misra, Shivangi; Gao, Yuchong; Lee, Young-Joo; Koditschek, Daniel E.; Yang, Shu; Sung, Cynthia R. (, IEEE Robotics and Automation Letters)
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